Search results for "crystallinity degree"

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Polypropylene/polyhedral oligomeric silsesquioxane nanocomposites – study of free volumes, crystallinity degree and mass flow rate

2016

Nanokompozyty polipropylen/poliedryczne oligomeryczne silseskwioksany (PP/POSS) przygotowano metodą mieszania w stanie stopionym polimeru. Wpływ struktury oraz ilości zastosowanych nanonapełniaczy POSS na objętości swobodne w polipropylenie określono z zastosowaniem spektroskopii czasów życia pozytonów (PALS). Ustalono zależności pomiędzy parametrami PALS: czasem życia o-Ps (τ3) i natężeniem (I3) składowej o-Ps oraz wartościami stopnia krystaliczności (Xc ) i masowego wskaźnika szybkości płynięcia (MFR) badanych materiałów. Obecność nanonapełniaczy POSS wpłynęła na liczbę i rozmiary objętości swobodnych w polimerze, co spowodowało zmianę mikrostruktury osnowy polipropylenowej. Wraz ze zwięk…

poliedryczne oligomeryczne silseskwioksany (POSS)Materials sciencePolymers and PlasticsGeneral Chemical Engineering02 engineering and technology010402 general chemistry01 natural sciencesDegree (temperature)chemistry.chemical_compoundCrystallinitymass flow ratenanocompositesMaterials ChemistryMass flow rateComposite materialnanokompozytyPolypropyleneNanocompositepositron annihilation lifetime spectroscopy (PALS)masowy wskaźnik szybkości płynięciacrystallinity degreestopień krystaliczności021001 nanoscience & nanotechnologySilsesquioxane0104 chemical scienceschemistryspektroskopia czasów życia pozytonów (PALS)polipropylen0210 nano-technologypolypropylenepolyhedral oligomeric silsesquioxanes (POSS)Polimery

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